Coffee science and gastronomy

Coffee Lipids and Grinders

extraction

Lipids are defined in chemistry as naturally occurring substances that insoluble in water but soluble in non-polar organic solvents. (Ether, alcohol, chloroform (CHCl3) ..)

Most commonly triacylglycerols, fatty acids and sterols are holding the higher percentages of lipids within green bean. However most of the oils/lipids are being pushed towards the outer layer of the coffee cells during roasting and degassing processes. This leads coffee to be oxidized rapidly and produce stale flavors and increase the thickness of the coffee grounds upon grinding.

Oxidation

Oxidation is typically defied as substance  losing electrons or gaining oxygen. Therefore once these coffee lipids get contacted with oxygen, through oxidation reactions staled and rancid flavours can be created within the coffee. Heat and moisture can increase the reaction rate of oxidation.

Rancidity Of Coffee 

Production of disagreeable aromas and flavours with the initiation of a chain reaction  via autoxidation of coffee’s fatty acids” can be defined as the rancidity of coffee.

The chain reaction starts when fatty acids get in contact with oxygen, hydroxide ion together as they imputed by energy of a photon. While brewing water provides the hydroxide ions, direct or diffuse light provide the energy of photons (E=hv)*. The unsaturated part of the fatty acid has the ability to discharge a proton (H+) once it has been act upon light. This proton together with hydroxide ion creates a water molecule while fatty acid generates a free acid radical (R-C-). Once this free radical gets in contact with oxygen in the air, it creates a fatty peroxyl (lipid peroxyl) radical (lipid peroxyl radical) (R-COO-). This free radical has the ability to get in action with another fatty acids’ C-H arm to break the bond by acting as an electrophilic addition in order to create another free acid radical (R-C-) which continues the propagation of the chain reaction

More about rancidity; (https://goo.gl/WyZJeN)

There are few coffee oils that play major role among others that we need to understand its’ behaviors and attributes to brew our coffees in best possible ways.

Stearic Acid (C18H36O2,  284.47724 g/mol)

imgsrv (2)

Oleic Acid (C18H34O2 , 282.46136 g/mol)

imgsrv (1)

Triglyceride (Trilinolein)( C57H98O6 879.38442 g/mol)

imgsrv

Glyceryl tripalmitate (C51H98O6 , 807.32022 g/mol)

imgsrv (3)

These oils are collectively response to heat in a very similar way. They have very high viscosity around room temperature. State solid at 0’C. However, when coffee beans are being grinded, due to heat of the constantly rotating burrs, this solid or very highly viscous states start to become liquidized (become fluid)(around 40’C-45’C). Then fluids these  start to flow through the micro cracks of the coffee cells towards the surface of the particle.

Now we come to the most interesting scenario,where these lipids are present in fluid form, stickiness of them can hold the ground coffee particles together and create clusters of coffee particles within the dose. Theses clusters will obstruct the flow rate of the water through the coffee bed. This phenomenon can cause uneven peroration at coffee brewing because of the hydraulic interferences and more likely to result an over extracted brew with highly oxidized flavour compounds that can create rancidity and staleness within the brew.

Therefore, it’s a major point that we need to understand that higher temperatures of grinder burrs upon grinding can create unevenly extracted, rancid brews where blaming the coffee origins, roasters or farmers will not be validated.


(Special thanks to http://pubchem.ncbi.nlm.nih.gov/ for pictures of the molecular structures)
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